브롬화 인화물

Phosphide bromide

브롬화물 또는 브롬화물 인화물은 브롬화물(Br−)과 인화물(P3−) 음이온으로 이루어진 음이온을 함유하는 화합물이다.보통 인은 보다 복잡한 구조로 공유적으로 연결되어 있다.이들은 혼합 음이온 화합물로 간주될 수 있다.그것들은 pnictidehalides의 범주에 속합니다.관련 화합물로는 염화인화물, 요오드화인화물, 브롬화질소, 브롬화비소 및 브롬화 안티몬화물이 있다.

목록.

공식 시스템. 스페이스 그룹 단위 셀 † 용량 밀도 댓글 레퍼런스
Ca2PBr 입방체의 I43d a=5.96 Z=2 적갈색 [1]
Ca2PBr 육각형의 R3m a=4.23 c=20.9 Z=3 [1]
Cu12P20Br10 삼사정형의 P a = 9.886, b = 13.199, c = 14.763, α = 70.83°, β = 82.68°, β = 80.13°, Z = 2 1786.1 [2]
Cu13P15Br12 [3]
Cu6PS5Br 입방체의 P43m a=9.732 Z=4 921.8 4.701 빨간. [4]
(CuBr)2PSE83 직교 혈전성 Pbcm a=8.761 b=11.957 c=13.858 Z=4 1451.8 [5]
Sr2PBr 입방체의 I43d a=9.31 Z=2 브라운 바이올렛 [1]
Sr2PBr 육각형의 R3m a=4.44 c=22.0 Z=3 짙은 적갈색 [1]
Sr2P7Br 입방체의 P213 a=9.789 Z=4 938.0 3.342 빨간색 밴드갭 2.1 eV [6]
Y2PBr2 마름모꼴의 a=3.9807 c=29.250 [7]
Ag6PS5Br 입방체의 P43m a=10.3765 Z=4 1117.26 5.460 빨간. [4]
Cd5P2Br4 직교 혈전성 Pna21 a=12.199, b=7.7080, c=13.664 [8]
Sn24P19.3Br8 [9]
Sn17Zn7P22Br8 입방체의 Pm3n a=10.7449 [10]
SnInP24−xx19.2+0.2x x <16 입방체의 Pm3n [11]
SiPTeBr30+x16–x8–xx x = 1 ~6.4 입방체의 Pm3n a=9.9720 - 10.0405 [12]
Ba2PBr 육각형의 R3m a=4.67 c=23.3 Z=3 [1]
Ba2P7Br 단사정형의 P21/m a=6.294 b=6.835 c=11.850 β=95.819 Z=2 507.2 3.742 오렌지색 [13]
La2PBr2 삼각형의 P3m1 a=4.311 c=11.000 Z=1 177.04 5.28 [7]
La3Zn4P6.6Br0.8 직교 혈전성 cmcm a=4.099 b=14.229 c=20.388 Z=4 1189.0 5.290 블랙입니다. [14]
Eu2PBr R3m a = 4.385, c = 21.90, Z = 3 [15]
W4(PBR)Br10 단사정형의 C12/m1 a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 1715.16 짙은 녹색 [16]
Hg2P3Br 직교 혈전성 Pbcn a = 8.014, b = 8.902, c = 7.823, Z = 4 [17]
Hg7P4Br6 단사정형의 P21/c a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 879.3 7.582 갈색 [18]
(Hg2P)2HgBr4 단사정형의 P21 a=7.776 b=12.226 c=7.930 β=180.34 Z=2 643.9 7.141 1907년에 발견되다; 밝은 노란색; 빛에 민감한 공기 [19]
[Hg7P4Br3](SnBr3) 입방체의 P213 a=12.490 Z=4 [20]

레퍼런스

  1. ^ a b c d e Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01). "Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium". Zeitschrift für Naturforschung B. 30 (5–6): 378–384. doi:10.1515/znb-1975-5-616. ISSN 1865-7117. S2CID 94967271.
  2. ^ Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.). "Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer". Zeitschrift für Kristallographie - Crystalline Materials. 212 (2): 103–109. Bibcode:1997ZK....212..103F. doi:10.1524/zkri.1997.212.2.103. ISSN 2194-4946.
  3. ^ Freudenthaler, E (November 1997). "Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors". Solid State Ionics. 101–103: 1053–1059. doi:10.1016/S0167-2738(97)00169-0.
  4. ^ a b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.
  5. ^ Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004). "(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs". Journal of Molecular Structure. 706 (1–3): 89–94. Bibcode:2004JMoSt.706...89N. doi:10.1016/j.molstruc.2004.01.037.
  6. ^ Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140.
  7. ^ a b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
  8. ^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd5P2Br4 - the first cadmium analogue of salts of Millon's base" [Cd5P2Br4 - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.
  9. ^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.
  10. ^ Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005). "Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures". Solid State Sciences. 7 (8): 957–968. doi:10.1016/j.solidstatesciences.2005.04.002.
  11. ^ Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.
  12. ^ Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05). "Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties". Inorganic Chemistry. 51 (21): 11396–11405. doi:10.1021/ic3010097. ISSN 0020-1669. PMID 23072375.
  13. ^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.
  14. ^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
  15. ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
  16. ^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669.
  17. ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
  18. ^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.
  19. ^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.
  20. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.