옥살산인산염

Oxalate phosphite

옥살산인산염은 옥살산염과 인산 음이온을 포함한 화합물이다.그것들은 또한 옥살라토인산염 또는 인산염이라고 불립니다.옥살산염은 금속 유기 골격 화합물을 형성할 수 있다.

관련 화합물로는 아질산 옥살산염, 아비산 옥살산염,[1][2] 인산염 옥살산염 및 옥살라토포스폰산염이 있다.

옥살산 이온은 직사각형이고 평면이다.인산 이온은 삼각형 피라미드 모양을 하고 있다.전하량이 많고 모양이 딱딱하기 때문에 여러 개의 양이온, 특히 +3과 같이 전하량이 높은 양이온에 브리지합니다.수소는 음이온에 있는 산소 중 일부를 OH로 전환시켜 전하를 줄일 수 있다.많은 옥살산인산염 화합물은 아민이 구조 [3]형성을 지시하는 미세공 구조를 가지고 있다.

목록.

이름. 화학 물질 음 결정계 스페이스 그룹 단위 셀 † 용량 밀도 댓글 레퍼런스
peha = 펜타에틸렌헥사민 [(흐흐흐6)]0.17HO2)]1.5 [Al2(HPO3)(2CO24)(HCOO)] +포맷 [4]
(HCNOH135)(0.5HCHN213142)[0.25Al2(HPO3)(2CO24)(OH)(HO2)] 0.5호2 [4]
Li2(VOHPO3)2 CO24•6호2 삼사정형의 P1 a=6.352, b=8.0789, c=9.162, α=64.390°, β=87.277°, β=67.624° [5]
Li2(VOHPO3)2 CO24•4호2 단사정형의 P21/a a=6.355 b=12.6368 c=9.0242 β=105.165° [5]
Li2(VO)(2HPO3)2 CO24 [6]
디아모늄(μ-옥살라토)-비스(μ-옥살라토)-다이옥소디-바나듐 수화물 (NH4)(2VOHPO3)2 CO24 2/9호2 삼사정형의 P1 a = 6.3844, b = 7.2278, c = 9.2965, α = 67.260°, β = 72.927°, β = 85.848° [7]
(μ-옥살라토6)-비스(μ-수소4 포스포나토)-비스(μ-아쿠아2)-비스(μ-옥소2)-디-나트륨-디-바나듐 Na2(VO)(2HPO3)2 CO24 463.87 삼사정형의 P1 a 6.3255 b 6.7760 c 8.0759, α 104.992° β 101.679° ≤ 99.120° Z=1 319.20 2.413 파랑색 [6]
K2(VO)(2HPO3)2 CO24 514.10 단사정형의 C2/c a 17.75 b 6.17 c 13.977, β 115.42° Z=4 1427 2.393 파랑색 [6]
KMn2II2(HO2)2 CO24(HPO3)2 472.09 육각형의 P63/m a=9.1991 c=22.4924 1846.8 2.547 핑크색 [8]
(CN3H6)2·Mn2.5(HPO3)(C2O4)2.5(H2O)·H2O [9]
피페라진 [CNH4212] [MnII2(HPO3)(2CO24)] 단사정형의 P21/c a=6.0627 b=10.7122 c=10.387 β=97.956 Z=2 668.1 2.217 연분홍색 [10]
탭 = 1,4-디아미노부탄 H2dab·Mn2(HPO3)2(C2O4)(H2O)2 단사정형의 P21/n a = 5.616, b = 15.431, c = 9.445, β = 91.72(2)°, Z = 2 818.2 [11]
인산망간옥살산에틸렌디아모늄 [CNH2210] [Mn2II(OH2)(2HPO3)(2CO24)] 단사정형의 P21/c a 7.837 b 8.755 c 10.100, β 100.605° [12]
비스(1-(3-글루시오프로필)이미다졸륨)테트라키스(μ-이수소포스파토)테트라키스(μ-옥살라토)테트라카탄 H2api·Mn2(H2PO4)2(C2O4)2 삼사정형의 P1 a=7.6108 b=9.8476 c=15.2437, α=100.023°β=102.032°θ=110.612° [13]
(C6H14N2)0.5Mn(H2PO3)(C2O4) [14]
1,4-디아자비시클로[2.2.2]옥탄(DABCO) [CNH6214]2 [FeFIII22(HPO3)(2CO24)]·22호2 단사정형의 P21/n a=12.51 b=6.372 c=33.199 β=90.532 Z=4 2643.0 1.875 무채색 [15]
트렌 [CNH6421]2 [FeII4(HPO3)(2CO24)]·55호2 삼사정형의 P1 a=8.719 b=8.827 c=15.908 α=78.617 β=84.047 δ=68.241 Z=2 1114.1 1.770 갈색, 네트워크 [15]
[FeIII2(OH2)2(HPO3)2(C2O4)]·호2 단사정형의 P21/c a=4.875 b=17.707 c=6.984 β=180.728 Z=4 577.46 2.368 무채색의 [15]
에틸렌디아모늄 [CNH2210] [FeII2(OH2)(2HPO3)(2CO24)] 단사정형의 P21/c a=7.684 b=8.651 c=10.053 β=100.821 Z=4 653.6 2.317 갈색 [15]
바펜 [CNH8426] [FeIII6(HPO3)(8CO24)]3 · 4호2 단사정형의 P21/n a=8.493 b=16.685 c=16.215 β=95.919 Z=4 2280.35 2.157 무채색의 [15]
호모핀 [CNH5214] [FeII4(HPO3)(2CO24)]3 단사정형의 P21/c a=7.682 b=7.726 c=18.092 β=94.443 Z=4 1070.8 2.004 갈색 [15]
피페라지네디움비스(μ-포스피토4)-(μ-옥살라토4)-비스(μ-옥살라토3)-테트라-철(ii) [CNH4212] [FeII4(HPO3)(2CO24)]3 단사정형의 P21/c a 7.7286 b 7.587 c 17.9816 β 98.214° [16]
탭 = 1,4-디아미노부탄 (H2dab)0.5·Co(H2PO3)(C2O4) [17]
[CNH4212] [Co4(HPO3)(2CO24)]3 단사정형의 P21/c a=7.614 b=7.51 c=17.750 β=97.351 Z=2 1007.3 2.466 [18]
CN3H6·Co(H2PO3)(C2O4) [8]
Co(H2PO3)(C2O4)·(C2H8N) 삼사정형의 P1 [19]
Co(H2PO3)(C2O4)·(C2H8N) 단사정형의 P21/n [19]
Co2(H2PO3)2(C2O4)3(C6N2H16)2 단사정형의 P21/c a=5.8605 b=13.6144 c=19.361

β=105.582

 1487.9 1.733 핑크색 [20]
Co2(H2PO3)2(C2O4)2(C6N2H16) 단사정형의 P21/c a=15.3007 b=8.2832 c=16.2601 β=182.487 Z=2 1890 2.010 핑크, 양성자 전도체 [20]
(C4H14N2)0.5Co(HPO3)(C2O4) [14]
비스(1,4-디아조니아비시클로[2.2]옥탄)비스(μ-수소포스피토3)-디히드록시비스(옥살라토)-디갈륨(iii) 이수화물 (C6N2H14)2[Ga2(OH)2(C2O4)2(HPO3)2]·2호2 단사정형의 P21/n a 12.401 b 6.283 c 33.306 β 91.199° [21]
N, N, N', N'-테트라메틸레틸렌디아모늄비스(μ-수소3 포스피토)-(μ-옥살라토2)-디히드록시디-갈륨(iii) (C6N2H18)0.5[Ga(OH)(C2O4)0.5(HPO3)] 삼사정형의 P1 a 6.257 b 8.558 c 9.253 α 93.219° β 108.265° γ 106.956° [21]
비스(μ-수소3 포스피토)-(μ-옥살라토2)-비스(1H-이미다졸)-디-갈륨(ii) Ga(C2O4)0.5(C3N2H4)(HPO3) 단사정형의 P21/c a 8.038 b 8.709 c 11.487, β 91.85° [21]
Ga(HPO3)(C2O4)(C3N2H4)·(C3N2H5) 직교 혈전성 Pnma a=13.288, b=6.361, c=1.5364, Z=4 [22]
[비스(1,4-디메틸피페라지네디움)테트라키스(μ-아세틸피페라지네디움2)-테트라키스(μ-아세틸피페라지네티오)-비스22(μ-옥살라토)-테트라키움] [Ga2(HPO3)2(H2PO3)2(C2O4)](C6N2H16) 단사정형의 P21/c a =10.199 b =12.525 c=16.295 β=98.218° [23]
[헤미키스(1,4-디메틸피페라지네디움) 비스(μ-아미노3)-(μ-옥살라토22)-디-아미노] [Ga2(HPO3)2(H2PO3)(C2O4)](C6N2H16)0.5 단사정형의 C 2/c a = 23.462 b = 8.1170 c = 16.898, β 112.873° [23]
펜 = 1,10-페난트로린 Cd2(phen)2(H2PO4)(H2PO3)(C2O4) 체인 [17]
Cd(C10H8N2)(HPO3)(C2O4)0.5 [14]
카테나-(피페라지네디움비스(μ-수소3 포스피토)-(μ-옥살라토2)-(μ-수소2 포스피토)-디-인듐) [CHN4122] [인2(HPO3)(3CO24)] 직교 혈전성 cmcm a=6.555 b=15.384 c=18.135 [24]
[CNH4212]3 [인2(HPO3)(2CO24)]44호2 [25]
1,4-나트륨 아비시클로 [2.2.2]옥탄(나트륨코) CHN6142 [인2(HPO3)(3CO24)] 671.79 직교 혈전성 Pna21 a = 12.414, b = 7.7166, c = 18.327, Z = 4 1755.6 2.542 [26]
[CNH4212]2 [인2(HPO3)(3CO24)]23호2 [25]
[CNH4212]3 [인4(HPO3)(6CO24)]3 [25]
[CNH4214] [In4(HO2)(HPO3)(5CO24)]22호2 [25]
H[In5(HPO3)6(H2PO3)2(C2O4)2]·(C4N2H11)2·호2 삼사정형의 P1 a =7.822 b =10.626 c =13.199, α =94.196°β =92.336° θ =110.181° [27]
1-메틸피페라진 입력5(HPO3)(6HPO1.53)(2CO24)·(2HCNH25212)2 삼사정형의 P1 a 10.1574 b 10.4440 c 10.6857, α 70.006° β 76.100° ≤ 79.337° [28]
1-에틸피페라진 입력5(HPO3)(6HPO1.53)(2CO24)·(2HCNH26214)2 삼사정형의 P1 a 10.19 b 10.4327 c 10.7158, α 69.373° β 77.168° γ 79.268° [28]
dbu = 1,8-디옥타비시클로 [5.4.0]디옥타비시-7-ene Hdbu·In2(HPO3)2(C2O4)1.5 [17]
Ba2(C2O4)(H2PO3)2 531.38 단사정형의 C2/c a = 12.3829, b = 7.9124, c = 11.0858, β = 182.788 (2)°, Z = 4 986.10 3.534 무채색의 [29]
[Pr(H2O)(C2O4)0.5(HPO3)]·호2 300.93 삼사정형의 P1 a=6.6764 b=7.0684 c=7.8103 α=124.199°β=95.415°θ=90.457°Z=2 2.923 [30]
[Nd(H2O)(C2O4)0.5(HPO3)]·호2 304.26 삼사정형의 P1 a=6.6544 b=7.0684 c=7.8103 α=182.160°β=95.307°θ=90.590°Z=2 2.985 [30]
[Sm(H2O)(C2O4)0.5(HPO3)]·호2 [30]
[Eu(H2O)(C2O4)0.5(HPO3)]·호2 311.98 삼사정형의 P1 a=6.5619 b=6.9442 c=7.7412 α=180.369°β=95.495°θ=90.824°Z=2 3.173 [30]
[Gd(H2O)(C2O4)0.5(HPO3)]·호2 317.27 삼사정형의 P1 a=6.5434 b=6.9311 c=7.7465 α=124.487°β=95.645°θ=90.833°Z=2 3.244 [30]
[호(HO2)(CO24)(0.5HPO3)]호2 324.95 삼사정형의 P1 a=6.4628 b=6.8519 c=7.6936 α=180.646°β=95.779°θ=91.028°Z=2 3.421 [30]
[Er(H2O)(C2O4)0.5(HPO3)]·호2 327.28 삼사정형의 P1 a=6.4400 b=6.8326 c=7.6747 α=124.654°β=95.757°θ=91.096°Z=2 3.487 [30]
[Tm(H2O)(C2O4)0.5(HPO3)]·호2 삼사정형의 P1 [30]
[YB(HO2)(CO24)(0.5HPO3)]호2 333.06 삼사정형의 P1 a=6.4075 b=6.8050 c=7.6647 α=132.753°β=95.858°θ=91.199°Z=2 3.589 [30]
[Lu(H2O)(C2O4)0.5(HPO3)]·호2 삼사정형의 P1 [30]

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