아르세니도스탄산염

Arsenidostannate

비소산염은 주석과 비소가 결합된 음이온을 포함하는 화합물이다.그것들은 테트라르세니드, pnictidostancate 또는 테트라플루닉티드의 범주에 속합니다.

이들은 양이온 하중이 주석 또는 [1]비소의 하중을 초과하는 팔라스타나이드(Pd(Sn,3As8))와 같은 비화물 스타니드와 구별됩니다.비소와 주석을 함유하는 다른 광물로는 어니글라이트와[2] [3]코이라이트가 있다.

이름. 공식 공식

체중

 크리스탈

시스템.

 공간

그룹.

 단위 셀 용량 밀도 평. 레퍼런스
Li1–xSn2+xAs2, 0.2 < x < 0.4 삼각형의 R3m a=3.991-4.0244 c=25.592-25.632 Z=3 353.6-358.9 [4]
나스나스22 I41/acd a = 14.191, c = 21.191, Z = 32 메탈릭 그레이 [5]
나스나스22 마름모꼴의 R3m a=4.000 c=27.562 금속, 층 [6]
KSn3As3 직교 혈전성 Pnma Z=4 밴드갭 0.50 eV [7]
RbSn3As3 직교 혈전성 Pnma a=10.321, b=4.0917, c=19.570 [7]
Ca5Sn2As6 직교 혈전성 빠밤 a = 13.643, b = 11.830, c = 4.140 Z=2 [8]
α-Sr3Sn2As4 직교 혈전성 Cmca a = 25.798, b = 12.888, c = 19.199, Z = 24 6358.8 용융 1185K, 밴드갭 0.9eV [9]
β-Sr3Sn2As4 단사정형의 P21/c a = 7.705, b = 19.199, c = 7.688, β = 112.003°, Z = 4 1049.9 dec>800K, 밴드갭 0.9eV [9]
Sr14Sn3As12 삼각형의 R3 Z=3 [10]
바스나스346 단사정형의 P21/n a=8.637, b=18.354, c=9.721, β=90.05°, Z=4 [11]
BaCu6Sn2As4−x 사각형 I4/mm a = 4.120, c = 24.088 [12]
Ba13Si6Sn8As22 4551.72 사각형 I42m a = 14.4857, c = 13.5506 Z = 2 2843.4 5.316 검정, SiAs410 유닛, 밴드갭 1.0 eV [13]
EuSn2As2 삼각형의 [14]
Eu14Sn3As12 삼각형의 R3 Z=3 [10]
Eu11Zn4Sn2As12 3069.46 단사정형의 C2/c a = 7.5679, b = 13.0883, c = 31.305, β = 94.8444 Z=4 3089.7 6.599 은, 밴드 갭 0.04 eV, 15K 미만 강자성, 음의 거대 자기 저항 [15]

레퍼런스

  1. ^ "Palarstanide Mineral Data". webmineral.com. Retrieved 8 December 2021.
  2. ^ "Erniggliite Mineral Data". webmineral.com. Retrieved 8 December 2021.
  3. ^ "Coiraite Mineral Data". webmineral.com. Retrieved 8 December 2021.
  4. ^ Lee, Kathleen; Kaseman, Derrick; Sen, Sabyasachi; Hung, Ivan; Gan, Zhehong; Gerke, Birgit; Pöttgen, Rainer; Feygenson, Mikhail; Neuefeind, Jörg; Lebedev, Oleg I.; Kovnir, Kirill (2015-03-18). "Intricate Short-Range Ordering and Strongly Anisotropic Transport Properties of Li 1– x Sn 2+ x As 2". Journal of the American Chemical Society. 137 (10): 3622–3630. doi:10.1021/jacs.5b00237. ISSN 0002-7863. OSTI 1334418. PMID 25702752.
  5. ^ Asbrand, Matthias; Eisenmann, Brigitte (1993). [ISSN: 0932-0776 "Na2[SnAs2], the first Zintl phase with a [SnAs2] framework based on adamantane analogous [Sn4As10] units"]. Zeitschrift fuer Naturforschung, B: Chemical Sciences. 48: 452–456. doi:10.1515/znb-1993-0409. S2CID 95169843. {{cite journal}}:확인. url=값(도움말)
  6. ^ Arguilla, Maxx Q.; Katoch, Jyoti; Krymowski, Kevin; Cultrara, Nicholas D.; Xu, Jinsong; Xi, Xiaoxiang; Hanks, Amanda; Jiang, Shishi; Ross, Richard D.; Koch, Roland J.; Ulstrup, Søren (2016-10-25). "NaSn 2 As 2 : An Exfoliatable Layered van der Waals Zintl Phase". ACS Nano. 10 (10): 9500–9508. arXiv:1710.09059. doi:10.1021/acsnano.6b04609. ISSN 1936-0851. PMID 27700035. S2CID 20747874.
  7. ^ a b Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt3As3 (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.
  8. ^ Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (November 1985). "Ca5Sn2As6, das erste Inoarsenidostannat(IV)". Zeitschrift für anorganische und allgemeine Chemie (in German). 530 (11): 74–78. doi:10.1002/zaac.19855301108. ISSN 0044-2313.
  9. ^ a b Liu, Xiao-Cun; Pan, Ming-Yan; Li, Xin; Xia, Sheng-Qing; Tao, Xu-Tang (2014). "Synthesis, polymorphism, and electronic structures of Sr 3 Sn 2 As 4". Inorg. Chem. Front. 1 (9): 689–694. doi:10.1039/C4QI00106K. ISSN 2052-1553.
  10. ^ a b Liu, Xiao-Cun; Pan, Ming-Yan; Xia, Sheng-Qing; Tao, Xu-Tang (21 September 2015). "Sr 14 Sn 3 As 12 and Eu 14 Sn 3 As 12 : Enantiomorph-like Zintl Compounds". Inorganic Chemistry. 54 (18): 8875–8877. doi:10.1021/acs.inorgchem.5b01145. PMID 26361335.
  11. ^ Lam, Robert; Mar, Arthur (May 2001). "The metallic Zintl phase Ba3Sn4As6". Solid State Sciences. 3 (4): 503–512. Bibcode:2001SSSci...3..503L. doi:10.1016/S1293-2558(01)01155-4.
  12. ^ Wu, Hanlin; Li, Sheng; Wang, Xiqu; Kwon, Sunah; Liu, Wenhao; Ofenstein, Gareth A.; Kim, Moon J.; Lv, Bing (February 2022). "New layered quaternary BaCu6Sn2As4−x and BaCu6Sn2P4−x phases: Crystal growth and physical properties". Journal of Alloys and Compounds. 892: 162111. doi:10.1016/j.jallcom.2021.162111. S2CID 239061015.
  13. ^ Liu, Xiao-Cun; Lin, Na; Wang, Jian; Pan, Ming-Yan; Zhao, Xian; Tao, Xu-Tang; Xia, Sheng-Qing (2013-10-21). "Ba 13 Si 6 Sn 8 As 22 : A Quaternary Zintl Phase Containing Adamantane-Like [Si 4 As 10 ] Clusters". Inorganic Chemistry. 52 (20): 11836–11842. doi:10.1021/ic402023z. ISSN 0020-1669. PMID 24079277.
  14. ^ Pakhira, Santanu; Tanatar, M. A.; Heitmann, Thomas; Vaknin, David; Johnston, D. C. (2021-11-19). "A -type antiferromagnetic order and magnetic phase diagram of the trigonal Eu spin- 7 2 triangular-lattice compound EuSn 2 As 2". Physical Review B. 104 (17): 174427. arXiv:2106.10519. Bibcode:2021PhRvB.104q4427P. doi:10.1103/PhysRevB.104.174427. ISSN 2469-9950. S2CID 235489681.
  15. ^ Devlin, Kasey P.; Kazem, Nasrin; Zaikina, Julia V.; Cooley, Joya A.; Badger, Jackson R.; Fettinger, James C.; Taufour, Valentin; Kauzlarich, Susan M. (2018-10-23). "Eu 11 Zn 4 Sn 2 As 12 : A Ferromagnetic Zintl Semiconductor with a Layered Structure Featuring Extended Zn 4 As 6 Sheets and Ethane-like Sn 2 As 6 Units". Chemistry of Materials. 30 (20): 7067–7076. doi:10.1021/acs.chemmater.8b02749. ISSN 0897-4756. S2CID 105572581.