댄하이저 고리
Danheiser annulationDanheiser 고리 또는 Danheiser TMS-cyclopentene 고리화는 Lewis 산의 존재 하에서 α,β-불포화 케톤과 트리알킬실릴렌(예를 들어 트리메틸실릴릴릴- 또는 트리이소프로필실릴릴-)의 유기 반응으로 트리알킬실리실리엔을 시클로펜텐으로 제어한다.
레퍼런스
- ^ R. L. Danheiser; D. J. Carini; A. Basak (1981). "TMS-Cyclopentene Annulation: A Regiocontrolled Approach to the Synthesis of Five-Membered Rings". J. Am. Chem. Soc. 103 (6): 1604. doi:10.1021/ja00396a071.
- ^ R. L. Danheiser; D. J. Carini; D. M. Fink; A. Basak (1983). "Scope and Stereochemical Course of the (Trimethylsilyl)cyclopentene Annulation". Tetrahedron. 39 (6): 935. doi:10.1016/S0040-4020(01)88592-6.
- ^ R. L. Danheiser; D. M. Fink (1985). "The Reaction of Allenysilanes with α,β-Unsaturated Acylsilanes: New Annulation Approaches to Five and Six-Membered Carbocyclic Compounds". Tetrahedron Letters. 26 (21): 2513. doi:10.1016/S0040-4039(00)98824-5.
- ^ R. L. Danheiser; D. M. Fink; Y. -M. Tsai (1988). "A General [3+2] Annulation: cis-4-Exo-isopropenyl-1,9-dimethyl-8-(trimethylsilyl)bicyclo-[4.3.0]non-8-en-2-one". Organic Syntheses. 66: 8. doi:10.15227/orgsyn.066.0008.
- ^ Alfred Hassner; C. Stumer (2002). Organic Syntheses Based on Name Reactions. Elsevier. ISBN 008043259X.
- ^ Jie Jack Li (2003). Name Reactions: A Collection of Detailed Reaction Mechanisms. Springer. p. 102. ISBN 3540402039.